Bubbles emerging from a submerged granular bed

This paper explores the phenomena associated with the emergence of gas bubbles from a submerged granular bed. While there are many natural and industrial applications, we focus on the particular circumstances and consequences associated with the emergence of methane bubbles from the beds of lakes and reservoirs since there are significant implications for the dynamics of lakes and reservoirs and for global warming. This paper describes an experimental study of the processes of bubble emergence from a granular bed. Two distinct emergence modes are identified, mode 1 being simply the percolation of small bubbles through the interstices of the bed, while mode 2 involves the cumulative growth of a larger bubble until its buoyancy overcomes the surface tension effects. We demonstrate the conditions dividing the two modes (primarily the grain size) and show that this accords with simple analytical evaluations. These observations are consistent with previous studies of the dynamics of bubbles within porous beds. The two emergence modes also induce quite different particle fluidization levels. The latter are measured and correlated with a diffusion model similar to that originally employed in river sedimentation models by Vanoni and others. Both the particle diffusivity and the particle flux at the surface of the granular bed are measured and compared with a simple analytical model. These mixing processes can be consider applicable not only to the grains themselves, but also to the nutrients and/or contaminants within the bed. In this respect they are shown to be much more powerful than other mixing processes (such as the turbulence in the benthic boundary layer) and could, therefore, play a dominant role in the dynamics of lakes and reservoirs

Pre-service teachers’ self-efficacy, attitudes and academic performance with regard to undergraduate research modules

The South African schooling system does not sufficiently prepare students for the demands raised by higher education institutions (HEIs). This study investigates the important role that self-efficacy and attitude play in determining pre-service teachers’ performance within research modules at private HEIs. Almost 90% of final year education students (n = 128) at private HEIs, emphasise their dislike for research. They also express their struggle in understanding research modules and how they relate to the teaching profession. This concurrent mixed-method study uses qualitative research to help explain quantitative findings regarding pre-service teachers’ challenges and concerns with regard to research modules. The study also determines pre-service teachers’ self-efficacy and attitude by administering a survey before the module and qualitative questionnaire upon completion of the research module. By determining pre-service teachers’ self-efficacy and attitude, the effectiveness of the research modules is also determined. The relationship between pre-service teachers’ self-efficacy, attitude and research module performance as part of the B.Ed. curriculum is established. The generic nature of undergraduate research modules allows for this case study’s purpose to be transferred to any other discipline or HEI. This study contributes to the advancement of institutional research across HEIs and stimulates interdisciplinary engagement within the field of research modules in South Africa

Overcoming the false-minima problem in direct methods: Structure determination of the packaging enzyme P4 from bacteriophage φ13

The problems encountered during the phasing and structure determination of the packaging enzyme P4 from bacteriophage φ13 using the anomalous signal from selenium in a single-wavelength anomalous dispersion experiment (SAD) are described. The oligomeric state of P4 in the virus is a hexamer (with sixfold rotational symmetry) and it crystallizes in space group C2, with four hexamers in the crystallographic asymmetric unit. Current state-of-the-art ab initio phasing software yielded solutions consisting of 96 atoms arranged as sixfold symmetric clusters of Se atoms. However, although these solutions showed high correlation coefficients indicative that the substructure had been solved, the resulting phases produced uninterpretable electron-density maps. Only after further analysis were correct solutions found (also of 96 atoms), leading to the eventual identification of the positions of 120 Se atoms. Here, it is demonstrated how the difficulties in finding a correct phase solution arise from an intricate false-minima problem. © 2005 International Union of Crystallography - all rights reserved

Structure factor and thermodynamics of rigid dendrimers in solution

The ''polymer reference interaction site model'' (PRISM) integral equation theory is used to determine the structure factor of rigid dendrimers in solution. The theory is quite successful in reproducing experimental structure factors for various dendrimer concentrations. In addition, the structure factor at vanishing scattering vector is calculated via the compressibility equation using scaled particle theory and fundamental measure theory. The results as predicted by both theories are systematically smaller than the experimental and PRISM data for platelike dendrimers.Comment: 7 pages, 5 figures, submitte

Information requirements for supersonic transport operation Final report

Effects of meteorological parameters and instrument errors on vertical flight performance of supersonic transport

Unexpected Effect of Internal Degrees of Freedom on Transverse Phonons in Supercooled Liquids

We show experimentally that in a supercooled liquid composed of molecules with internal degrees of freedom the internal modes contribute to the frequency dependent shear viscosity and damping of transverse phonons, which results in an additional broadening of the transverse Brillouin lines. Earlier, only the effect of internal modes on the frequency dependent bulk viscosity and damping of longitudinal phonons was observed and explained theoretically in the limit of weak coupling of internal degrees of freedom to translational motion. A new theory is needed to describe this new effect. We also demonstrate, that the contributions of structural relaxation and internal processes to the width of the Brillouin lines can be separated by measurements under high pressure

Large-area sheet task advanced dendritic web growth development

The computer code for calculating web temperature distribution was expanded to provide a graphics output in addition to numerical and punch card output. The new code was used to examine various modifications of the J419 configuration and, on the basis of the results, a new growth geometry was designed. Additionally, several mathematically defined temperature profiles were evaluated for the effects of the free boundary (growth front) on the thermal stress generation. Experimental growth runs were made with modified J419 configurations to complement the modeling work. A modified J435 configuration was evaluated